Call me old fashioned but I'm a copper guy. I keep thinking in ten more years they will realize PEX leaches bad chemicals into the water.
Yup!
Our water did smell and taste funny for almost 6 months after we got PEX!
OTOH copper isn't too awfully healthy either and if you have acidic water you get really nasty reactions and toxic chemicals in the water. I've seen that once with well water and every tub/shower/sink turned blue-green. Not good!
Among all plastics I've heard of, polyethylene seems to be the least problematic. I don't like new materials in critical applications as a rule though - copper plumbing pipe has been around here for more than 50 years, so I'd say it has stood the test of time provided it's properly soldered.
In the larger cities here they still haven't managed to get rid of all of the soft lead plumbing! Especially risers in multi-family buildings are rarely ever replaced at all because you have to tear up all apartments at the same time and at least some tenants usually run amok.